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Silver Art
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Silver chloride (AgCl) is precipitated from solutions of silver nitrate in the presence of chloride ions, and the other silver halides used in the manufacture of photographic emulsions are made in the same way, using bromide or iodide salts. Silver chloride is used in glass electrodes for pH testing and potentiometric measurement, and as a transparent cement for glass. Silver iodide has been used in attempts to seed clouds to produce rain. Silver halides are highly insoluble in aqueous solutions and are used in gravimetric analytical methods.
Silver oxide (Ag2O), produced when silver nitrate solutions are treated with a base, is used as a positive electrode (anode) in watch batteries. Silver carbonate (Ag2CO3) is precipitated when silver nitrate is treated with sodium carbonate (Na2CO3).
2 AgNO3 + 2 OH- → Ag2O + H2O + 2 NO3-
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