Silver Art

Silver fulminate (AgONC), a powerful, touch-sensitive explosive used in percussion caps, is made by reaction of silver metal with nitric acid in the presence of ethanol (C2H5OH). Another dangerously explosive silver compound is silver azide (AgN3), formed by reaction of silver nitrate with sodium azide (NaN3).
Latent images formed in silver halide crystals are developed by treatment with alkaline solutions of reducing agents such as hydroquinone, metol (4-(methylamino)phenol sulfate) or ascorbate, which reduce the exposed halide to silver metal. Alkaline solutions of silver nitrate can be reduced to silver metal by reducing sugars such as glucose, and this reaction is used to silver glass mirrors and the interior of glass Christmas ornaments. Silver halides are soluble in solutions of sodium thiosulfate (Na2S2O3) which is used as a photographic fixer, to remove excess silver halide from photographic emulsions after image development.
Silver metal is attacked by strong oxidizers such as potassium permanganate (KMnO4) and potassium dichromate (K2Cr2O7), and in the presence of potassium bromide (KBr), these compounds are used in photography to bleach silver images, converting them to silver halides that can either be fixed with thiosulfate or redeveloped to intensify the original image. Silver forms cyanide complexes (silver cyanide) that are soluble in water in the presence of an excess of cyanide ions. Silver cyanide solutions are used in electroplating of silver.